A Biocatalytic Aza-Achmatowicz Reaction

Elena Fernández-Fueyo; Sabry H H Younes; Stefan Van Rootselaar; René W M Aben; Rokus Renirie; Ron Wever; Dirk Holtmann; Floris P J T Rutjes; Frank Hollmann

doi:10.1021/acscatal.6b01636

A Biocatalytic Aza-Achmatowicz Reaction

Elena Fernández-Fueyo, Sabry H H Younes, Stefan Van Rootselaar, René W M Aben, Rokus Renirie, Ron Wever, Dirk Holtmann, Floris P J T Rutjes^*, Frank Hollmann

^*Corresponding author for this work

BT/Biocatalysis

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Abstract

A catalytic, enzyme-initiated (aza-) Achmatowicz reaction is presented. The involvement of a robust vanadium-dependent peroxidase from Curvularia inaequalis allows the simple use of H₂O₂ and catalytic amounts of bromide.

Original language	English
Pages (from-to)	5904-5907
Number of pages	4
Journal	ACS Catalysis
Volume	6
Issue number	9
DOIs	https://doi.org/10.1021/acscatal.6b01636
Publication status	Published - 2016

Bibliographical note

Accepted Author Manuscript

Keywords

Achmatowicz reaction
biocatalysis
hypohalogenites
oxidation
peroxidase

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10.1021/acscatal.6b01636

cs-2016-00313m revisedAccepted author manuscript, 526 KB

Cite this

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title = "A Biocatalytic Aza-Achmatowicz Reaction",

abstract = "A catalytic, enzyme-initiated (aza-) Achmatowicz reaction is presented. The involvement of a robust vanadium-dependent peroxidase from Curvularia inaequalis allows the simple use of H2O2 and catalytic amounts of bromide.",

keywords = "Achmatowicz reaction, biocatalysis, hypohalogenites, oxidation, peroxidase",

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AU - Fernández-Fueyo, Elena

AU - Younes, Sabry H H

AU - Van Rootselaar, Stefan

AU - Aben, René W M

AU - Renirie, Rokus

AU - Wever, Ron

AU - Holtmann, Dirk

AU - Rutjes, Floris P J T

AU - Hollmann, Frank

N1 - Accepted Author Manuscript

PY - 2016

Y1 - 2016

N2 - A catalytic, enzyme-initiated (aza-) Achmatowicz reaction is presented. The involvement of a robust vanadium-dependent peroxidase from Curvularia inaequalis allows the simple use of H2O2 and catalytic amounts of bromide.

AB - A catalytic, enzyme-initiated (aza-) Achmatowicz reaction is presented. The involvement of a robust vanadium-dependent peroxidase from Curvularia inaequalis allows the simple use of H2O2 and catalytic amounts of bromide.

KW - Achmatowicz reaction

KW - biocatalysis

KW - hypohalogenites

KW - oxidation

KW - peroxidase

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JO - ACS Catalysis

JF - ACS Catalysis

IS - 9

ER -

A Biocatalytic Aza-Achmatowicz Reaction

Abstract

Bibliographical note

Keywords

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