TY - JOUR
T1 - A Photochemoenzymatic Hunsdiecker-Borodin-Type Halodecarboxylation of Ferulic Acid
AU - Zippilli, Claudio
AU - Bartolome, Miguel Jimenez
AU - Hilberath, Thomas
AU - Botta, Lorenzo
AU - Hollmann, Frank
AU - Saladino, Raffaele
PY - 2022
Y1 - 2022
N2 - A photochemoenzymatic halodecarboxylation of ferulic acid was achieved using vanadate-dependent chloroperoxidase as (bio)catalyst and oxygen and organic solvent as sole stoichiometric reagents in a biphasic system. Performance and selectivity were improved through a phase transfer catalyst, reaching a turnover number of 660.000 for the enzyme.
AB - A photochemoenzymatic halodecarboxylation of ferulic acid was achieved using vanadate-dependent chloroperoxidase as (bio)catalyst and oxygen and organic solvent as sole stoichiometric reagents in a biphasic system. Performance and selectivity were improved through a phase transfer catalyst, reaching a turnover number of 660.000 for the enzyme.
KW - halodecarboxylation
KW - phase-transfer catalysis
KW - photobiocatalysis
KW - photochemoenzymatic reactions
KW - vanadium chloroperoxidase
UR - http://www.scopus.com/inward/record.url?scp=85136468861&partnerID=8YFLogxK
U2 - 10.1002/cbic.202200367
DO - 10.1002/cbic.202200367
M3 - Article
C2 - 35921215
AN - SCOPUS:85136468861
SN - 1439-4227
VL - 23
JO - ChemBioChem
JF - ChemBioChem
IS - 19
M1 - e202200367
ER -