A solvent-free synthesis of (thio)ester derivatives using FeCl3 as a heterogeneous catalyst

Sabry H.H. Younes; F. Hollmann

doi:10.1016/j.tetlet.2023.154524

A solvent-free synthesis of (thio)ester derivatives using FeCl₃ as a heterogeneous catalyst

Sabry H.H. Younes^*, F. Hollmann

^*Corresponding author for this work

BT/Biocatalysis

Research output: Contribution to journal › Article › Scientific › peer-review

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Abstract

A simple, solvent-free method for the synthesis of (thio)esters from simple acid chlorides at room temperature is reported. Simple FeCl₃ (5 mol%) enables facile, near complete conversion of equimolar starting materials in high selectivity. Recycling of the catalyst has been demonstrated.

Original language	English
Article number	154524
Journal	Tetrahedron Letters
Volume	123
DOIs	https://doi.org/10.1016/j.tetlet.2023.154524
Publication status	Published - 2023

Keywords

FeCl
Thioester

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10.1016/j.tetlet.2023.154524

1-s2.0-S0040403923002198-mainFinal published version, 0.99 MBLicence: CC BY

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title = "A solvent-free synthesis of (thio)ester derivatives using FeCl3 as a heterogeneous catalyst",

abstract = "A simple, solvent-free method for the synthesis of (thio)esters from simple acid chlorides at room temperature is reported. Simple FeCl3 (5 mol%) enables facile, near complete conversion of equimolar starting materials in high selectivity. Recycling of the catalyst has been demonstrated.",

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AU - Younes, Sabry H.H.

AU - Hollmann, F.

PY - 2023

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N2 - A simple, solvent-free method for the synthesis of (thio)esters from simple acid chlorides at room temperature is reported. Simple FeCl3 (5 mol%) enables facile, near complete conversion of equimolar starting materials in high selectivity. Recycling of the catalyst has been demonstrated.

AB - A simple, solvent-free method for the synthesis of (thio)esters from simple acid chlorides at room temperature is reported. Simple FeCl3 (5 mol%) enables facile, near complete conversion of equimolar starting materials in high selectivity. Recycling of the catalyst has been demonstrated.

KW - FeCl

KW - Thioester

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U2 - 10.1016/j.tetlet.2023.154524

DO - 10.1016/j.tetlet.2023.154524

M3 - Article

AN - SCOPUS:85156238591

SN - 0040-4039

VL - 123

JO - Tetrahedron Letters

JF - Tetrahedron Letters

M1 - 154524

ER -

A solvent-free synthesis of (thio)ester derivatives using FeCl₃ as a heterogeneous catalyst

Abstract

Keywords

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