An alginate-confined peroxygenase-CLEA for styrene epoxidation

Friederike E.H. Nintzel, Yinqi Wu, Matteo Planchestainer, Martin Held, Miguel Alcalde, Frank Hollmann*

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

1 Citation (Scopus)
10 Downloads (Pure)

Abstract

Oxyfunctionalisation reactions in neat substrate still pose a challenge for biocatalysis. Here, we report an alginate-confined peroxygenase-CLEA to catalyse the enantioselective epoxidation of cis-β-methylstyrene in a solvent-free reaction system achieving turnover numbers of 96 000 for the biocatalyst and epoxide concentrations of 48 mM.

Original languageEnglish
Pages (from-to)5766-5769
Number of pages4
JournalChemical Communications
Volume57
Issue number47
DOIs
Publication statusPublished - 2021

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