An Interface Co-modification Strategy for Improving the Efficiency and Stability of CsPbI3Perovskite Solar Cells

Hui Guan, Yutian Lei, Qiyuan Wu, Xufeng Zhou, Haoxu Wang, Gang Wang, Wenquan Li, Zhiwen Jin*, Wei Lan

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

Abstract

Interface engineering is a simple and effective strategy for improving the photovoltaic performance and stability of perovskite solar cells (PSCs). Herein, an interface co-modification strategy is proposed, using [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) and 2-fluoro-1,4-phenylenediammonium iodide (2FPPD) to modify the electron transport layer (ETL)/perovskite (PVK) and the PVK/hole transport layer (HTL) interfaces, respectively. A series of characterizations demonstrate that the PCBM&2FPPD interface co-modification strategy effectively enhances the extraction and transport efficiency of carriers at the interface, passivates surface defects, inhibits the nonradiative recombination of carriers, and simultaneously inhibits ion migration. Moreover, this strategy improves the crystallinity and surface hydrophobicity of PVK and optimizes the energy level alignment of PSCs. As a result, all photovoltaic parameters are improved after optimization, where the power conversion efficiency (PCE) of PSCs has increased from 17.01% to 18.36%. Meanwhile, the optimized PSCs show excellent environmental stability, which can be stably stored in air (RH = 10-20%) for about 800 h.

Original languageEnglish
Pages (from-to)13419-13428
Number of pages10
JournalACS Applied Energy Materials
Volume5
Issue number11
DOIs
Publication statusPublished - 2022

Bibliographical note

Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care
Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.

Keywords

  • CsPbI
  • defect passivation
  • interface engineering
  • perovskite solar cell
  • photovoltaic performance
  • stability

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