TY - JOUR
T1 - Application of Classical Thermodynamics to Conductivity in Nonpolar Media: Experimental Confirmation
T2 - The Journal of Physical Chemistry B
AU - Gourdin-Bertin, S.
AU - Chassagne, C.
N1 - Accepted author manuscript
PY - 2018
Y1 - 2018
N2 - We previously proposed (Gourdin-Bertin, S. and Chassagne, C. J. Chem. Phys. 2016, 144 (24)) a simple theoretical model to account for the evolution of conductivity with dielectric permittivity in nonpolar media. In this article, we validate the theory experimentally for the case of an ionogenic species kept at a constant chemical potential (i.e., in equilibrium with a nondissolved salt, in contrast to previously published conductivity measurements carried out as a function of various fully dissolved salt concentrations). To our knowledge, it is the first time that this type of experiment has been performed explicitly.
AB - We previously proposed (Gourdin-Bertin, S. and Chassagne, C. J. Chem. Phys. 2016, 144 (24)) a simple theoretical model to account for the evolution of conductivity with dielectric permittivity in nonpolar media. In this article, we validate the theory experimentally for the case of an ionogenic species kept at a constant chemical potential (i.e., in equilibrium with a nondissolved salt, in contrast to previously published conductivity measurements carried out as a function of various fully dissolved salt concentrations). To our knowledge, it is the first time that this type of experiment has been performed explicitly.
U2 - 10.1021/acs.jpcb.7b09061
DO - 10.1021/acs.jpcb.7b09061
M3 - Article
SN - 1520-6106
VL - 122
SP - 1223
EP - 1227
JO - The Journal of Physical Chemistry Part B (Biophysical Chemistry, Biomaterials, Liquids, and Soft Matter)
JF - The Journal of Physical Chemistry Part B (Biophysical Chemistry, Biomaterials, Liquids, and Soft Matter)
IS - 3
ER -