Application of Classical Thermodynamics to Conductivity in Nonpolar Media: Experimental Confirmation: The Journal of Physical Chemistry B

S. Gourdin-Bertin, C. Chassagne

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Abstract

We previously proposed (Gourdin-Bertin, S. and Chassagne, C. J. Chem. Phys. 2016, 144 (24)) a simple theoretical model to account for the evolution of conductivity with dielectric permittivity in nonpolar media. In this article, we validate the theory experimentally for the case of an ionogenic species kept at a constant chemical potential (i.e., in equilibrium with a nondissolved salt, in contrast to previously published conductivity measurements carried out as a function of various fully dissolved salt concentrations). To our knowledge, it is the first time that this type of experiment has been performed explicitly.
Original languageEnglish
Pages (from-to)1223-1227
Number of pages5
JournalThe Journal of Physical Chemistry Part B (Biophysical Chemistry, Biomaterials, Liquids, and Soft Matter)
Volume122
Issue number3
DOIs
Publication statusPublished - 2018

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