TY - JOUR
T1 - Author Correction
T2 - Coupling electrochemical CO2 conversion with CO2 capture (Nature Catalysis, (2021), 4, 11, (952-958), 10.1038/s41929-021-00699-7)
AU - Sullivan, Ian
AU - Goryachev, Andrey
AU - Digdaya, Ibadillah A.
AU - Li, Xueqian
AU - Atwater, Harry A.
AU - Vermaas, David A.
AU - Xiang, Chengxiang
N1 - Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care
Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.
Author correction to DOI 10.1038/s41929-021-00699-7
PY - 2022
Y1 - 2022
N2 - In the version of this article, there were errors in Fig. 2a and d. In Fig. 2a, we have changed Cu2+ to Cu(0) in the revised version. While the two references cited in our paper used Cu2+ in their schematics,1,2 we believe that Cu(0) is the correct representation for the electrochemically mediated amine regeneration (EMAR)3. To be clear, the Cu metal anode is oxidized into cupric ions. The cupric ions then bind to the carbamate and displace the CO2 and form a copper–amine complex. The copper–amine complex is then reduced at the cathode where Cu metal is plated out. In Fig. 2d, we have changed the polarity of the cathode and anode in the revised version. A proton is released at the anode, while a hydroxide is released at the cathode. We have also simplified the quinone/hydroquinone chemistry in the revised version to be consistent with proton and hydroxide stoichiometry. The original and revised Fig. 2 images are shown below. The changes have been made to the html and PDF versions of the article.
AB - In the version of this article, there were errors in Fig. 2a and d. In Fig. 2a, we have changed Cu2+ to Cu(0) in the revised version. While the two references cited in our paper used Cu2+ in their schematics,1,2 we believe that Cu(0) is the correct representation for the electrochemically mediated amine regeneration (EMAR)3. To be clear, the Cu metal anode is oxidized into cupric ions. The cupric ions then bind to the carbamate and displace the CO2 and form a copper–amine complex. The copper–amine complex is then reduced at the cathode where Cu metal is plated out. In Fig. 2d, we have changed the polarity of the cathode and anode in the revised version. A proton is released at the anode, while a hydroxide is released at the cathode. We have also simplified the quinone/hydroquinone chemistry in the revised version to be consistent with proton and hydroxide stoichiometry. The original and revised Fig. 2 images are shown below. The changes have been made to the html and PDF versions of the article.
UR - http://www.scopus.com/inward/record.url?scp=85123221952&partnerID=8YFLogxK
U2 - 10.1038/s41929-022-00734-1
DO - 10.1038/s41929-022-00734-1
M3 - Comment/Letter to the editor
AN - SCOPUS:85123221952
SN - 2520-1158
VL - 5
SP - 75
EP - 76
JO - Nature Catalysis
JF - Nature Catalysis
IS - 1
ER -