BiFeO3 synthesis by conventional solid-state reaction

A. Yu Tuluk; T. R. Mahon; S. Van Der Zwaag; Pim Groen

doi:10.1109/ISAF43169.2019.9034976

BiFeO₃ synthesis by conventional solid-state reaction

A. Yu Tuluk^*, T. R. Mahon, S. Van Der Zwaag, Pim Groen

^*Corresponding author for this work

Research output: Chapter in Book/Conference proceedings/Edited volume › Conference contribution › Scientific › peer-review

3 Citations (Scopus)

249 Downloads (Pure)

Abstract

BiFeO₃ is a multiferroic material with the perovskite structure which is promising for use in sensors and transducers. Single phase production of BiFeO₃ remains a challenge, however. In this study, the optimal calcination temperature to obtain close to single phase powder was determined to be 750°C. The sintering temperature of 775°C was also found to obtain high density ceramics (≈ 95 % of theoretical density). It is shown that off-stoichiometry of bismuth oxide in precursors effects the content of secondary phase. Impedance spectroscopy indicates that the content of secondary phases has a large effect on the electrical conductivity BiFeO₃.

Original language	English
Title of host publication	2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019 - Proceedings
Publisher	Institute of Electrical and Electronics Engineers (IEEE)
ISBN (Electronic)	9781538694640
DOIs	https://doi.org/10.1109/ISAF43169.2019.9034976
Publication status	Published - 2019
Event	2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019 - Lausanne, Switzerland Duration: 14 Jul 2019 → 19 Jul 2019

Publication series

Name	2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019 - Proceedings

Conference

Conference	2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019
Country/Territory	Switzerland
City	Lausanne
Period	14/07/19 → 19/07/19

Bibliographical note

Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care
Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.

Keywords

bismuth ferrite
impedance spectroscopy
multiferroic
perovskite
solid state reaction

Access to Document

10.1109/ISAF43169.2019.9034976

BiFeO3_synthesis_by_conventional_solid-state_reactionFinal published version, 1.35 MB

Cite this

Tuluk, A. Y., Mahon, T. R., Van Der Zwaag, S., & Groen, P. (2019). BiFeO₃ synthesis by conventional solid-state reaction. In 2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019 - Proceedings [9034976] (2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019 - Proceedings). Institute of Electrical and Electronics Engineers (IEEE). https://doi.org/10.1109/ISAF43169.2019.9034976

Tuluk, A. Yu ; Mahon, T. R. ; Van Der Zwaag, S. ; Groen, Pim. / BiFeO₃ synthesis by conventional solid-state reaction. 2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019 - Proceedings. Institute of Electrical and Electronics Engineers (IEEE), 2019. (2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019 - Proceedings).

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abstract = "BiFeO3 is a multiferroic material with the perovskite structure which is promising for use in sensors and transducers. Single phase production of BiFeO3 remains a challenge, however. In this study, the optimal calcination temperature to obtain close to single phase powder was determined to be 750°C. The sintering temperature of 775°C was also found to obtain high density ceramics (≈ 95 % of theoretical density). It is shown that off-stoichiometry of bismuth oxide in precursors effects the content of secondary phase. Impedance spectroscopy indicates that the content of secondary phases has a large effect on the electrical conductivity BiFeO3.",

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Tuluk, AY, Mahon, TR, Van Der Zwaag, S & Groen, P 2019, BiFeO₃ synthesis by conventional solid-state reaction. in 2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019 - Proceedings., 9034976, 2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019 - Proceedings, Institute of Electrical and Electronics Engineers (IEEE), 2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019, Lausanne, Switzerland, 14/07/19. https://doi.org/10.1109/ISAF43169.2019.9034976

BiFeO₃ synthesis by conventional solid-state reaction. / Tuluk, A. Yu; Mahon, T. R.; Van Der Zwaag, S.; Groen, Pim.

2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019 - Proceedings. Institute of Electrical and Electronics Engineers (IEEE), 2019. 9034976 (2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019 - Proceedings).

Research output: Chapter in Book/Conference proceedings/Edited volume › Conference contribution › Scientific › peer-review

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Tuluk AY, Mahon TR, Van Der Zwaag S, Groen P. BiFeO₃ synthesis by conventional solid-state reaction. In 2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019 - Proceedings. Institute of Electrical and Electronics Engineers (IEEE). 2019. 9034976. (2019 IEEE International Symposium on Applications of Ferroelectrics, ISAF 2019 - Proceedings). https://doi.org/10.1109/ISAF43169.2019.9034976