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Charge-ordering signatures in the optical properties of β-Na0.33V2O5

  • C. Presura*
  • , M. Popinciuc
  • , P. H.M. Van Loosdrecht
  • , D. Van der Marel
  • , M. Mostovoy
  • , T. Yamauchi
  • , Y. Ueda
  • *Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

Abstract

The temperature dependent optical conductivity of β-Na0.33V2O5 was studied. It was observed that both the midinfrared peak at 3000 cm-1 and the observation of strong electron-phonon coupling support the picture that the charge carriers in βNa0.33V2O5 should be regarded as small polarons. Furthermore, the strong Hubbard-type interactions brought about the independent behavior of the spin and charge channels at the metal-insulator phase transition.

Original languageEnglish
Article number026402
JournalPhysical review letters
Volume90
Issue number2
Publication statusPublished - 2003
Externally publishedYes

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