Abstract
A chemoenzymatic method for the halocyclization of unsaturated alcohols and acids by using the robust V-dependent chloroperoxidase from Curvularia inaequalis (CiVCPO) as catalyst has been developed for the in situ generation of hypohalites. A broad range of halolactones and cyclic haloethers are formed with excellent performance of the biocatalyst.
Original language | English |
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Pages (from-to) | 97-101 |
Number of pages | 5 |
Journal | ChemSusChem |
Volume | 13 |
Issue number | 1 |
DOIs | |
Publication status | Published - 2019 |
Keywords
- biocatalysis
- enzymes
- etherification
- haloperoxidases
- lactones