Effect of anodic aluminum oxide chemistry on adhesive bonding of epoxy

Shoshan Abrahami, T. Hauffman, JMM de Kok, Arjan Mol, Herman Terryn

    Research output: Contribution to journalArticlepeer-review

    41 Citations (Scopus)

    Abstract

    The transition to Cr(VI)-free production is a great challenge in the global aerospace industry that currently still relays on it for the preparation of aluminum for bonding. Proper surface pretreatment is a prerequisite for strong and durable adhesive joint. Despite decades of experience, the nature and contribution of the different adhesion forces between the aluminum and organic adhesive remain under discussion. Herein we studied the adhesion of epoxy resin as a function of the surface chemistry of barrier-type anodic oxides prepared in sulfuric acid (SAA), phosphoric acid (PAA), and mixtures of phosphoric–sulfuric acids (PSA) and chromic acid (CAA) at different anodizing temperatures. X-ray photoelectron spectroscopy (XPS) data measured on model specimens were curve-fitted to calculate the relative amounts of O2–, OH–, PO43–, and SO42– species at the surface. The amounts of these species were then related to the mechanical performance of the joint measured by the floating roller peel test. Results show that significant initial adhesion is achieved without mechanical interlocking and independent of the type of electrolytes used for the pretreatment. Conversely, bonding stability under wet conditions is highly influenced by the surface chemistry. The wet adhesion strength increases with the hydroxyl concentration at the aluminum (oxide) surface, indicating that interfacial bonding is established through these surface hydroxyls. Phosphates and sulfates anions were not found to contribute to bonding with this type of adhesive.
    Original languageEnglish
    Pages (from-to)19670–19677
    JournalThe Journal of Physical Chemistry C
    Volume120
    Issue number35
    DOIs
    Publication statusPublished - 2016

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