TY - JOUR
T1 - Effect of inter-electrode separation in the fabrication of nanoporous alumina by anodization
AU - Michalska-Domańska, Marta
AU - Stępniowski, Wojciech Jerzy
AU - Salerno, Marco
PY - 2018
Y1 - 2018
N2 - The effect of the separation between electrodes on the main output parameters of the anodic aluminum oxide structure, namely the pore size, the cell size, the thickness and the regularity ratio was investigated. Pure aluminum foils were anodized in 0.3 M oxalic acid at different combinations of electrode separations (1.5, 3 and 6 cm), anodization voltages (30, 45 and 60 V) and temperatures (10, 20 and 30 °C). Whereas cell size and thickness appeared to be independent on the electrode separation, minor effects emerged for the pore size and significant effects emerged for the regularity ratio. The latter decreased with electrode separation at the lowest anodization voltage, but increased for the other voltages, especially at intermediate value of 45 V. For the temperature series, the regularity ratio decreased with separation at highest and, mostly, lowest temperature, while increased at intermediate temperature. Therefore, in addition to the major fabrication parameters of anodization voltage, current density, temperature and electrolyte concentration, it appears that the electrode separation may also cause relevant effects on the pattern quality, which should be taken into account for careful control of this nanofabrication process.
AB - The effect of the separation between electrodes on the main output parameters of the anodic aluminum oxide structure, namely the pore size, the cell size, the thickness and the regularity ratio was investigated. Pure aluminum foils were anodized in 0.3 M oxalic acid at different combinations of electrode separations (1.5, 3 and 6 cm), anodization voltages (30, 45 and 60 V) and temperatures (10, 20 and 30 °C). Whereas cell size and thickness appeared to be independent on the electrode separation, minor effects emerged for the pore size and significant effects emerged for the regularity ratio. The latter decreased with electrode separation at the lowest anodization voltage, but increased for the other voltages, especially at intermediate value of 45 V. For the temperature series, the regularity ratio decreased with separation at highest and, mostly, lowest temperature, while increased at intermediate temperature. Therefore, in addition to the major fabrication parameters of anodization voltage, current density, temperature and electrolyte concentration, it appears that the electrode separation may also cause relevant effects on the pattern quality, which should be taken into account for careful control of this nanofabrication process.
KW - Anodic aluminum oxide
KW - Anodization
KW - Electrode separation
KW - Image analysis
KW - Nanopores
KW - Regularity ratio
KW - Scanning electron microscopy
UR - http://www.scopus.com/inward/record.url?scp=85048488217&partnerID=8YFLogxK
U2 - 10.1016/j.jelechem.2018.05.038
DO - 10.1016/j.jelechem.2018.05.038
M3 - Article
AN - SCOPUS:85048488217
SN - 1572-6657
VL - 823
SP - 47
EP - 53
JO - Journal of Electroanalytical Chemistry
JF - Journal of Electroanalytical Chemistry
ER -