Efficacious elimination of intramolecular charge transfer in perylene imide based light-harvesting antenna molecules

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Abstract

Two light-harvesting antenna molecules were obtained by positioning naphthalene monoimide energy donors at the imide position, instead of the bay positions, of perylene imide energy acceptors. Such rational design resulted in a complete suppression of parasitic intramolecular charge transfer without compromising the desired ultrafast rates of excitation energy transfer.

Original languageEnglish
Pages (from-to)5560-5563
JournalChemical communications (Cambridge, England)
Volume56
Issue number41
DOIs
Publication statusPublished - 2020

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