Abstract
A Ser105Ala mutant of the lipase B from Candida antarctica enables 'perhydrolase-only' reactions. At the example of the chemoenzymatic Baeyer-Villiger oxidation of cyclohexanone, we demonstrate that with this mutant selective oxidation can be achieved in deep eutectic solvent while essentially eliminating the undesired hydrolysis reaction of the product.
Original language | English |
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Article number | 44599 |
Number of pages | 5 |
Journal | Scientific Reports |
Volume | 7 |
DOIs | |
Publication status | Published - 20 Mar 2017 |