Facile Method for the Preparation of Covalent Triazine Framework coated Monoliths as Catalyst Support: Applications in C1 Catalysis

Anastasiya V. Bavykina, Alma I. Olivos-Suarez, Dmitrii Osadchii, Rahul Valecha, Robert Franz, Michiel Makkee, Freek Kapteijn, Jorge Gascon

Research output: Contribution to journalArticleScientificpeer-review

19 Citations (Scopus)
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Abstract

A quasi chemical vapor deposition method for the manufacture of well-defined covalent triazine framework (CTF) coatings on cordierite monoliths is reported. The resulting supported porous organic polymer is an excellent support for the immobilization of two different homogeneous catalysts: (1) an IrIIICp∗-based catalyst for the hydrogen production from formic acid and (2) a PtII-based catalyst for the direct activation of methane via Periana chemistry. The immobilized catalysts display a much higher activity in comparison with the unsupported CTF operated in slurry because of improved mass transport. Our results demonstrate that CTF-based catalysts can be further optimized by engineering at different length scales.

Original languageEnglish
Pages (from-to)26060-26065
Number of pages6
JournalACS Applied Materials and Interfaces
Volume9
Issue number31
DOIs
Publication statusPublished - 9 Aug 2017

Keywords

  • covalent triazine frameworks
  • hydrogen
  • methane
  • methanol
  • structured catalysts

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