Harnessing Plasticity in an Amine-Borane as a Piezoelectric and Pyroelectric Flexible Film

Yan Zhang; Margaret A. Hopkins; David J. Liptrot; Hamideh Khanbareh; Pim Groen; Xuefan Zhou; Dou Zhang; Yinxiang Bao; Kechao Zhou; Chris R. Bowen; David R. Carbery

doi:10.1002/anie.202001798

Harnessing Plasticity in an Amine-Borane as a Piezoelectric and Pyroelectric Flexible Film

Yan Zhang, Margaret A. Hopkins, David J. Liptrot^*, Hamideh Khanbareh, Pim Groen, Xuefan Zhou, Dou Zhang, Yinxiang Bao, Kechao Zhou, Chris R. Bowen, David R. Carbery

^*Corresponding author for this work

Aerospace Structures & Materials

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Abstract

We demonstrate that trimethylamine borane can exhibit desirable piezoelectric and pyroelectric properties. The material was shown to be able operate as a flexible film for both thermal sensing, thermal energy conversion and mechanical sensing with high open circuit voltages (>10 V). A piezoelectric coefficient of d₃₃≈10–16 pC N⁻¹, and pyroelectric coefficient of p≈25.8 μC m⁻² K⁻¹ were achieved after poling, with high pyroelectric figure of merits for sensing and harvesting, along with a relative permittivity of (Formula presented.) 6.3.

Original language	English
Pages (from-to)	7808-7812
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	59
Issue number	20
DOIs	https://doi.org/10.1002/anie.202001798
Publication status	Published - 2020

Bibliographical note

Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care
Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.

Keywords

energy conversion
flexible films
main group elements
piezoelectricity
pyroelectricity

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anie.202001798Final published version, 1.97 MB

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title = "Harnessing Plasticity in an Amine-Borane as a Piezoelectric and Pyroelectric Flexible Film",

abstract = "We demonstrate that trimethylamine borane can exhibit desirable piezoelectric and pyroelectric properties. The material was shown to be able operate as a flexible film for both thermal sensing, thermal energy conversion and mechanical sensing with high open circuit voltages (>10 V). A piezoelectric coefficient of d33≈10–16 pC N−1, and pyroelectric coefficient of p≈25.8 μC m−2 K−1 were achieved after poling, with high pyroelectric figure of merits for sensing and harvesting, along with a relative permittivity of (Formula presented.) 6.3.",

keywords = "energy conversion, flexible films, main group elements, piezoelectricity, pyroelectricity",

author = "Yan Zhang and Hopkins, {Margaret A.} and Liptrot, {David J.} and Hamideh Khanbareh and Pim Groen and Xuefan Zhou and Dou Zhang and Yinxiang Bao and Kechao Zhou and Bowen, {Chris R.} and Carbery, {David R.}",

note = "Green Open Access added to TU Delft Institutional Repository {\textquoteleft}You share, we take care!{\textquoteright} – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.",

year = "2020",

doi = "10.1002/anie.202001798",

language = "English",

volume = "59",

pages = "7808--7812",

journal = "Angewandte Chemie - International Edition",

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T1 - Harnessing Plasticity in an Amine-Borane as a Piezoelectric and Pyroelectric Flexible Film

AU - Zhang, Yan

AU - Hopkins, Margaret A.

AU - Liptrot, David J.

AU - Khanbareh, Hamideh

AU - Groen, Pim

AU - Zhou, Xuefan

AU - Zhang, Dou

AU - Bao, Yinxiang

AU - Zhou, Kechao

AU - Bowen, Chris R.

AU - Carbery, David R.

N1 - Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.

PY - 2020

Y1 - 2020

N2 - We demonstrate that trimethylamine borane can exhibit desirable piezoelectric and pyroelectric properties. The material was shown to be able operate as a flexible film for both thermal sensing, thermal energy conversion and mechanical sensing with high open circuit voltages (>10 V). A piezoelectric coefficient of d33≈10–16 pC N−1, and pyroelectric coefficient of p≈25.8 μC m−2 K−1 were achieved after poling, with high pyroelectric figure of merits for sensing and harvesting, along with a relative permittivity of (Formula presented.) 6.3.

AB - We demonstrate that trimethylamine borane can exhibit desirable piezoelectric and pyroelectric properties. The material was shown to be able operate as a flexible film for both thermal sensing, thermal energy conversion and mechanical sensing with high open circuit voltages (>10 V). A piezoelectric coefficient of d33≈10–16 pC N−1, and pyroelectric coefficient of p≈25.8 μC m−2 K−1 were achieved after poling, with high pyroelectric figure of merits for sensing and harvesting, along with a relative permittivity of (Formula presented.) 6.3.

KW - energy conversion

KW - flexible films

KW - main group elements

KW - piezoelectricity

KW - pyroelectricity

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DO - 10.1002/anie.202001798

M3 - Article

AN - SCOPUS:85082061254

SN - 1433-7851

VL - 59

SP - 7808

EP - 7812

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 20

ER -

Harnessing Plasticity in an Amine-Borane as a Piezoelectric and Pyroelectric Flexible Film

Abstract

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Keywords

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