Abstract
Taking advantage of the unique properties of two-component flavo-monooxygenases and the ability of [Cp*Ir(bpy-OMe)H]+ to transfer hydrides to reduce flavins, we extended the scope of the pH- and oxygen-robust iridium(iii)-complex to drive the enzymatic reaction of a FMN-dependent Baeyer-Villiger monooxygenase and a FAD-dependent styrene monooxygenase (respectively FPMO Group C and E), using formic acid as H-donor for NADH recycling.
Original language | English |
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Pages (from-to) | 3117-3123 |
Journal | Reaction Chemistry and Engineering |
Volume | 8 |
Issue number | 12 |
DOIs | |
Publication status | Published - 2023 |