Hydrogenation of Lactic Acid to 1,2-Propanediol over Ru-Based Catalysts

Kaituo Liu, Xiaoming Huang, Evgeny A. Pidko*, Emiel J.M. Hensen

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

19 Citations (Scopus)


The catalytic hydrogenation of lactic acid to 1,2-propanediol with supported Ru catalysts in water was investigated. The influence of catalyst support (activated carbon, γ-Al2O3, SiO2, TiO2, and CeO2) and promoters (Pd, Au, Mo, Re, Sn) on the catalytic performance was evaluated. Catalytic tests revealed that TiO2 yields the best Ru catalysts. With a monometallic Ru/TiO2 catalyst, a 1,2-propanediol yield of 70 % at 79 % lactic acid conversion was achieved at 130 °C after 20 h reaction. Minor byproducts of the hydrogenation reaction were propionic acid, ethanol, 1-propanol, and 2-propanol. For the bimetallic catalysts, the addition of Pd and Au slightly enhanced the performance of Ru/TiO2, whereas the addition of common hydrogenation promoters such as Re, Mo, and Sn impaired the activity.

Original languageEnglish
Pages (from-to)810-817
Issue number4
Publication statusPublished - 2018
Externally publishedYes


  • alcohols
  • carboxylic acids
  • hydrogenation
  • ruthenium
  • supported catalysts


Dive into the research topics of 'Hydrogenation of Lactic Acid to 1,2-Propanediol over Ru-Based Catalysts'. Together they form a unique fingerprint.

Cite this