In-Situ Infrared Spectroscopy Applied to the Study of the Electrocatalytic Reduction of CO2: Theory, Practice and Challenges

Recep Kas, Onagie Ayemoba, Nienke J. Firet, Joost Middelkoop, Wilson A. Smith, Angel Cuesta

Research output: Contribution to journalReview articleScientificpeer-review

23 Citations (Scopus)
3 Downloads (Pure)

Abstract

The field of electrochemical CO2 conversion is undergoing significant growth in terms of the number of publications and worldwide research groups involved. Despite improvements of the catalytic performance, the complex reaction mechanisms and solution chemistry of CO2 have resulted in a considerable amount of discrepancies between theoretical and experimental studies. A clear identification of the reaction mechanism and the catalytic sites are of key importance in order to allow for a qualitative breakthrough and, from an experimental perspective, calls for the use of in-situ or operando spectroscopic techniques. In-situ infrared spectroscopy can provide information on the nature of intermediate species and products in real time and, in some cases, with relatively high time resolution. In this contribution, we review key theoretical aspects of infrared reflection spectroscopy, followed by considerations of practical implementation. Finally, recent applications to the electrocatalytic reduction of CO2 are reviewed, including challenges associated with the detection of reaction intermediates.

Original languageEnglish
Pages (from-to)2904-2925
Number of pages22
JournalChemPhysChem
Volume20
Issue number22
DOIs
Publication statusPublished - 2019

Keywords

  • carbon dioxide
  • electrochemical CO reduction
  • in-situ infrared spectroscopy
  • SEIRAS
  • spectro-electrochemistry

Fingerprint Dive into the research topics of 'In-Situ Infrared Spectroscopy Applied to the Study of the Electrocatalytic Reduction of CO<sub>2</sub>: Theory, Practice and Challenges'. Together they form a unique fingerprint.

Cite this