Mechanical properties and healing efficiency of 3D-printed ABS vascular based self-healing cementitious composite: Experiments and modelling

Cracking is one of the main causes for deterioration of concrete structures. Self-healing concrete with 3D-printed vascular networks has excellent potential for autonomous self-healing. This approach is scarcely investigated: no studies have been devoted to the influence of printing parameters on the properties of vascular based self-healing concrete. In this work, three-dimensional vascular structures with complex geometry were designed and printed with 4 different sets of printing parameters. First, the influence of the four, nominally identical, vascular networks on the initial flexural strength of self-healing concretes was experimentally investigated. In parallel, numerical modeling with a concrete damaged plasticity model (CDPM) in Abaqus software is used to simulate the influence of vascular networks on the mechanical properties of the self-healing composite. After the 4-point bending tests, epoxy resin is injected into the vascular networks as the healing agent to seal the cracks. Then, flexural strength regain and watertightness recovery were also measured. Based on the obtained results, we found that vascular based self-healing concretes have lower initial flexural strengths than the reference sample, as expected. The magnitude of the strength drop is shown to depend strongly on the printing parameters: the specimens with horizontally-printed vascular networks have higher flexural strength than the vertically-printed counterparts. Furthermore, vascular networks with a smaller printing layer-height have less influence on the initial flexural strength of vascular-based self-healing concrete compared to those with the larger printing layer-height. In terms of watertightness recovery, all tested vascular based self-healing samples showed a full (100%) recovery, which means that the printing direction and printing layer-height do not have an obvious effect on the watertightness recovery in this study. Numerical simulations of the mechanical performance of the composites with the CDPM show good agreement with the experiments, although printing quality of the vascular network influences the simulation accuracy. These simulations show great potential of using numerical simulations to design vascular based self-healing concrete in order to minimize a drop in mechanical properties, without compromising the healing efficiency. Overall, the designed 3D-printed vascular self-healing concretes show remarkable strength regain and watertightness recovery and provide a good basis for further research.