Metal-hydrogen systems with an exceptionally large and tunable thermodynamic destabilization

Peter Ngene, Alessandro Longo, Lennard Mooij, Wim Bras, Bernard Dam

Research output: Contribution to journalArticleScientificpeer-review

19 Citations (Scopus)
51 Downloads (Pure)

Abstract

Hydrogen is a key element in the energy transition. Hydrogen-metal systems have been studied for various energy-related applications, e.g., for their use in reversible hydrogen storage, catalysis, hydrogen sensing, and rechargeable batteries. These applications depend strongly on the thermodynamics of the metal-hydrogen system. Therefore, tailoring the thermodynamics of metal-hydrogen interactions is crucial for tuning the properties of metal hydrides. Here we present a case of large metal hydride destabilization by elastic strain. The addition of small amounts of zirconium to yttrium leads to a compression of the yttrium lattice, which is maintained during (de)hydrogenation cycles. As a result, the equilibrium hydrogen pressure of YH2 → YH3 can be rationally and precisely tuned up to five orders of magnitude at room temperature. This allows us to realize a hydrogen sensor which indicates the ambient hydrogen pressure over four orders of magnitude by an eye-visible color change.

Original languageEnglish
Article number1846
Pages (from-to)1-8
Number of pages8
JournalNature Communications
Volume8
Issue number1
DOIs
Publication statusPublished - 1 Dec 2017

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