Natural Deep Eutectic Solvents as Performance Additives for Peroxygenase Catalysis

Yunjian Ma; Yongru Li; Shahid Ali; Peilin Li; Wuyuan Zhang; Marine C.R. Rauch; Sébastien J.P. Willot; Doris Ribitsch; Frank Hollmann; null More Authors

doi:10.1002/cctc.201901842

Natural Deep Eutectic Solvents as Performance Additives for Peroxygenase Catalysis

Yunjian Ma, Yongru Li, Shahid Ali, Peilin Li, Wuyuan Zhang, Marine C.R. Rauch, Sébastien J.P. Willot, Doris Ribitsch, Frank Hollmann^*, More Authors

^*Corresponding author for this work

BT/Biocatalysis

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Abstract

Natural deep eutectic solvents (NADES) are proposed as alternative solvents for peroxygenase-catalysed oxyfunctionalization reactions. Choline chloride-based NADES are of particular interest as they can serve as solvent, enzyme-stabiliser and sacrificial electron donor for the in situ H₂O₂ generation. This report provides the first proof-of-concept and basic characterisation of this new reaction system. Highly promising turnover numbers for the biocatalysts of up to 200,000 have been achieved.

Original language	English
Pages (from-to)	989-994
Number of pages	6
Journal	ChemCatChem
Volume	12
Issue number	4
DOIs	https://doi.org/10.1002/cctc.201901842
Publication status	Published - 2019

Keywords

Choline oxidase
Deep Eutectic Solvents
Oxyfunctionalisation reactions
Peroxygenases

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cctc.201901842Final published version, 1.64 MBLicence: CC BY

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title = "Natural Deep Eutectic Solvents as Performance Additives for Peroxygenase Catalysis",

abstract = "Natural deep eutectic solvents (NADES) are proposed as alternative solvents for peroxygenase-catalysed oxyfunctionalization reactions. Choline chloride-based NADES are of particular interest as they can serve as solvent, enzyme-stabiliser and sacrificial electron donor for the in situ H2O2 generation. This report provides the first proof-of-concept and basic characterisation of this new reaction system. Highly promising turnover numbers for the biocatalysts of up to 200,000 have been achieved.",

keywords = "Choline oxidase, Deep Eutectic Solvents, Oxyfunctionalisation reactions, Peroxygenases",

author = "Yunjian Ma and Yongru Li and Shahid Ali and Peilin Li and Wuyuan Zhang and Rauch, {Marine C.R.} and Willot, {S{\'e}bastien J.P.} and Doris Ribitsch and Frank Hollmann and {More Authors}",

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AU - Ma, Yunjian

AU - Li, Yongru

AU - Ali, Shahid

AU - Li, Peilin

AU - Zhang, Wuyuan

AU - Rauch, Marine C.R.

AU - Willot, Sébastien J.P.

AU - Ribitsch, Doris

AU - Hollmann, Frank

AU - More Authors, null

PY - 2019

Y1 - 2019

N2 - Natural deep eutectic solvents (NADES) are proposed as alternative solvents for peroxygenase-catalysed oxyfunctionalization reactions. Choline chloride-based NADES are of particular interest as they can serve as solvent, enzyme-stabiliser and sacrificial electron donor for the in situ H2O2 generation. This report provides the first proof-of-concept and basic characterisation of this new reaction system. Highly promising turnover numbers for the biocatalysts of up to 200,000 have been achieved.

AB - Natural deep eutectic solvents (NADES) are proposed as alternative solvents for peroxygenase-catalysed oxyfunctionalization reactions. Choline chloride-based NADES are of particular interest as they can serve as solvent, enzyme-stabiliser and sacrificial electron donor for the in situ H2O2 generation. This report provides the first proof-of-concept and basic characterisation of this new reaction system. Highly promising turnover numbers for the biocatalysts of up to 200,000 have been achieved.

KW - Choline oxidase

KW - Deep Eutectic Solvents

KW - Oxyfunctionalisation reactions

KW - Peroxygenases

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DO - 10.1002/cctc.201901842

M3 - Article

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SN - 1867-3880

VL - 12

SP - 989

EP - 994

JO - ChemCatChem

JF - ChemCatChem

IS - 4

ER -

Natural Deep Eutectic Solvents as Performance Additives for Peroxygenase Catalysis

Abstract

Keywords

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