Natural Deep Eutectic Solvents as Performance Additives for Peroxygenase Catalysis

Yunjian Ma, Yongru Li, Shahid Ali, Peilin Li, Wuyuan Zhang, Marine C.R. Rauch, Sébastien J.P. Willot, Doris Ribitsch, Frank Hollmann*, More Authors

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

7 Citations (Scopus)
37 Downloads (Pure)

Abstract

Natural deep eutectic solvents (NADES) are proposed as alternative solvents for peroxygenase-catalysed oxyfunctionalization reactions. Choline chloride-based NADES are of particular interest as they can serve as solvent, enzyme-stabiliser and sacrificial electron donor for the in situ H2O2 generation. This report provides the first proof-of-concept and basic characterisation of this new reaction system. Highly promising turnover numbers for the biocatalysts of up to 200,000 have been achieved.

Original languageEnglish
Pages (from-to)989-994
Number of pages6
JournalChemCatChem
Volume12
Issue number4
DOIs
Publication statusPublished - 2019

Keywords

  • Choline oxidase
  • Deep Eutectic Solvents
  • Oxyfunctionalisation reactions
  • Peroxygenases

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