One- and two-electron reduction of molybdate reversibly bound to the archaeal tungstate/molybdate transporter WtpA

Loes E. Bevers, Wilfred R. Hagen

Research output: Contribution to journalArticleScientificpeer-review

4 Citations (Scopus)

Abstract

Reversible binding of the tetrahedral oxoanions MoO4 2- and WO4 2- to two carboxylato ligands of the soluble scavenger protein WtpA from the hyperthermophilic archaeon Pyrococcus furiosus enforces a quasi-octahedral MO6 coordination in which the +VI oxidation state is destabilized.

Original languageEnglish
Pages (from-to)8168-8170
Number of pages3
JournalDalton Transactions: the international journal for inorganic, organometallic and bioinorganic chemistry
Issue number39
DOIs
Publication statusPublished - 2009

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