Putting the RAFT in GRAFT: intermolecular graft exchange between bottlebrush polymers using reversible addition–fragmentation chain transfer

Satu  Häkkinen; W.E. Dyer; Andrew  Kerr; Sébastien  Perrier

doi:10.1039/d1py01510a

Putting the RAFT in GRAFT: intermolecular graft exchange between bottlebrush polymers using reversible addition–fragmentation chain transfer

Satu Häkkinen, W.E. Dyer, Andrew Kerr, Sébastien Perrier

Research output: Contribution to journal › Article › Scientific › peer-review

11 Citations (Scopus)

Abstract

A versatile synthetic methodology is presented for the preparation of graft copolymers with mixed graft distributions using reversible addition–fragmentation chain transfer (RAFT). The approach harnesses the ability of Z group-tethered grafts to fragment off the backbone to facilitate intermolecular graft exchange reactions between distinct starting materials.

Original language	English
Pages (from-to)	479-484
Number of pages	6
Journal	Polymer Chemistry
Volume	13
Issue number	4
DOIs	https://doi.org/10.1039/d1py01510a
Publication status	Published - 2022
Externally published	Yes

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10.1039/d1py01510a

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title = "Putting the RAFT in GRAFT: intermolecular graft exchange between bottlebrush polymers using reversible addition–fragmentation chain transfer",

abstract = "A versatile synthetic methodology is presented for the preparation of graft copolymers with mixed graft distributions using reversible addition–fragmentation chain transfer (RAFT). The approach harnesses the ability of Z group-tethered grafts to fragment off the backbone to facilitate intermolecular graft exchange reactions between distinct starting materials.",

author = "Satu H{\"a}kkinen and W.E. Dyer and Andrew Kerr and S{\'e}bastien Perrier",

year = "2022",

doi = "10.1039/d1py01510a",

language = "English",

volume = "13",

pages = "479--484 ",

journal = "Polymer Chemistry",

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publisher = "Royal Society of Chemistry",

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T1 - Putting the RAFT in GRAFT

T2 - intermolecular graft exchange between bottlebrush polymers using reversible addition–fragmentation chain transfer

AU - Häkkinen, Satu

AU - Dyer, W.E.

AU - Kerr, Andrew

AU - Perrier, Sébastien

PY - 2022

Y1 - 2022

N2 - A versatile synthetic methodology is presented for the preparation of graft copolymers with mixed graft distributions using reversible addition–fragmentation chain transfer (RAFT). The approach harnesses the ability of Z group-tethered grafts to fragment off the backbone to facilitate intermolecular graft exchange reactions between distinct starting materials.

AB - A versatile synthetic methodology is presented for the preparation of graft copolymers with mixed graft distributions using reversible addition–fragmentation chain transfer (RAFT). The approach harnesses the ability of Z group-tethered grafts to fragment off the backbone to facilitate intermolecular graft exchange reactions between distinct starting materials.

UR - https://www.scopus.com/pages/publications/85123913417

U2 - 10.1039/d1py01510a

DO - 10.1039/d1py01510a

M3 - Article

SN - 1759-9954

VL - 13

SP - 479

EP - 484

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 4

ER -

Putting the RAFT in GRAFT: intermolecular graft exchange between bottlebrush polymers using reversible addition–fragmentation chain transfer

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