TY - JOUR
T1 - Reaction conditions effect and pathways in the oxidative steam reforming of raw bio-oil on a Rh/CeO2-ZrO2 catalyst in a fluidized bed reactor
AU - Arandia, Aitor
AU - Remiro, Aingeru
AU - Oar-Arteta Gonzalez, L.
AU - Bilbao, Javier
AU - Gayubo, Ana G.
N1 - Accepted Author Manuscript
PY - 2017
Y1 - 2017
N2 - A reaction scheme has been proposed for the oxidative steam reforming (OSR) of raw bio-oil on a Rh/CeO2-ZrO2 catalyst, based on the study of the effect reaction conditions (temperature, space time, oxygen/carbon ratio and steam/carbon ratio) have on product yields (H2, CO, CO2, CH4, hydrocarbons). The runs were performed in a two-step system, with separation of pyrolytic lignin (first step) followed by catalytic reforming in a fluidized bed reactor (second step), under a wide range of reaction conditions (600–750 °C; space time, 0.15–0.6 gcatalysth/gbio-oil; oxygen to carbon molar ratio (O/C), 0–0.67; steam to carbon molar ratio (S/C), 3–9). The catalyst is very active for bio-oil reforming, and produces high H2 yield (between 0.57 and 0.92), with low CO yield (0.035–0.175) and CH4 yield (below 0.045) and insignificant light hydrocarbons formation. The proposed reaction scheme considers the catalyzed reactions (reforming, water gas shift (WGS) and combustion) and the thermal routes (decomposition/cracking and combustion). The deactivation of the catalyst affects progressively the reactions in the following order: CH4 reforming, hydrocarbons reforming, oxygenates reforming, combustion and WGS.
AB - A reaction scheme has been proposed for the oxidative steam reforming (OSR) of raw bio-oil on a Rh/CeO2-ZrO2 catalyst, based on the study of the effect reaction conditions (temperature, space time, oxygen/carbon ratio and steam/carbon ratio) have on product yields (H2, CO, CO2, CH4, hydrocarbons). The runs were performed in a two-step system, with separation of pyrolytic lignin (first step) followed by catalytic reforming in a fluidized bed reactor (second step), under a wide range of reaction conditions (600–750 °C; space time, 0.15–0.6 gcatalysth/gbio-oil; oxygen to carbon molar ratio (O/C), 0–0.67; steam to carbon molar ratio (S/C), 3–9). The catalyst is very active for bio-oil reforming, and produces high H2 yield (between 0.57 and 0.92), with low CO yield (0.035–0.175) and CH4 yield (below 0.045) and insignificant light hydrocarbons formation. The proposed reaction scheme considers the catalyzed reactions (reforming, water gas shift (WGS) and combustion) and the thermal routes (decomposition/cracking and combustion). The deactivation of the catalyst affects progressively the reactions in the following order: CH4 reforming, hydrocarbons reforming, oxygenates reforming, combustion and WGS.
KW - Bio-oil
KW - Hydrogen
KW - Oxidative steam reforming
KW - Reaction scheme
KW - Rh catalyst
UR - http://resolver.tudelft.nl/uuid:fa6d5dc4-b7ac-4b36-af6c-df6bc710a220
UR - http://www.scopus.com/inward/record.url?scp=85032884228&partnerID=8YFLogxK
U2 - 10.1016/j.ijhydene.2017.10.095
DO - 10.1016/j.ijhydene.2017.10.095
M3 - Article
AN - SCOPUS:85032884228
SN - 0360-3199
VL - 42
SP - 29175
EP - 29185
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
IS - 49
ER -