Selective Photooxidation Reactions using Water-Soluble Anthraquinone Photocatalysts

Wuyuan Zhang; Jenő Gacs; Isabel W.C.E. Arends; Frank Hollmann

doi:10.1002/cctc.201700779

Selective Photooxidation Reactions using Water-Soluble Anthraquinone Photocatalysts

Wuyuan Zhang^*
, Jenő Gacs
, Isabel W.C.E. Arends
, Frank Hollmann

^*Corresponding author for this work

BT/Biocatalysis

Research output: Contribution to journal › Article › Scientific › peer-review

81 Citations (Scopus)

119 Downloads (Pure)

Abstract

The aerobic organocatalytic oxidation of alcohols was achieved by using water-soluble sodium anthraquinone sulfonate. Under visible-light activation, this catalyst mediated the aerobic oxidation of alcohols to aldehydes and ketones. The photo-oxyfunctionalization of alkanes was also possible under these conditions.

Original language	English
Pages (from-to)	3821-3826
Number of pages	6
Journal	ChemCatChem
Volume	9
Issue number	20
DOIs	https://doi.org/10.1002/cctc.201700779
Publication status	Published - 2017

Keywords

alcohols
organocatalysis
oxidation
oxyfunctionalization
photocatalysis

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Zhang_et_al-2017-ChemCatChemFinal published version, 1.34 MBLicence: CC BY-NC-ND

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title = "Selective Photooxidation Reactions using Water-Soluble Anthraquinone Photocatalysts",

abstract = "The aerobic organocatalytic oxidation of alcohols was achieved by using water-soluble sodium anthraquinone sulfonate. Under visible-light activation, this catalyst mediated the aerobic oxidation of alcohols to aldehydes and ketones. The photo-oxyfunctionalization of alkanes was also possible under these conditions.",

keywords = "alcohols, organocatalysis, oxidation, oxyfunctionalization, photocatalysis",

author = "Wuyuan Zhang and Jen{\H o} Gacs and Arends, \{Isabel W.C.E.\} and Frank Hollmann",

year = "2017",

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language = "English",

volume = "9",

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journal = "ChemCatChem",

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T1 - Selective Photooxidation Reactions using Water-Soluble Anthraquinone Photocatalysts

AU - Zhang, Wuyuan

AU - Gacs, Jenő

AU - Arends, Isabel W.C.E.

AU - Hollmann, Frank

PY - 2017

Y1 - 2017

N2 - The aerobic organocatalytic oxidation of alcohols was achieved by using water-soluble sodium anthraquinone sulfonate. Under visible-light activation, this catalyst mediated the aerobic oxidation of alcohols to aldehydes and ketones. The photo-oxyfunctionalization of alkanes was also possible under these conditions.

AB - The aerobic organocatalytic oxidation of alcohols was achieved by using water-soluble sodium anthraquinone sulfonate. Under visible-light activation, this catalyst mediated the aerobic oxidation of alcohols to aldehydes and ketones. The photo-oxyfunctionalization of alkanes was also possible under these conditions.

KW - alcohols

KW - organocatalysis

KW - oxidation

KW - oxyfunctionalization

KW - photocatalysis

UR - http://resolver.tudelft.nl/uuid:39065192-188b-4f46-a92e-2a5d7baf330b

UR - https://www.scopus.com/pages/publications/85028921402

U2 - 10.1002/cctc.201700779

DO - 10.1002/cctc.201700779

M3 - Article

AN - SCOPUS:85028921402

SN - 1867-3880

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EP - 3826

JO - ChemCatChem

JF - ChemCatChem

IS - 20

ER -

Selective Photooxidation Reactions using Water-Soluble Anthraquinone Photocatalysts

Abstract

Keywords

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