TY - JOUR
T1 - Silicon Heterojunction Solar Cells Featuring Localized Front Contacts
AU - Smits, Sebastian
AU - Zhao, Yifeng
AU - Procel Moya, Paul
AU - Mazzarella, Luana
AU - Isabella, Olindo
PY - 2025
Y1 - 2025
N2 - Throughout the development of silicon heterojunction (SHJ) solar cells, the transparent conductive oxide has been regarded as an essential component of their front electrode, facilitating lateral charge transport of photogenerated carriers toward the front metal grid fingers. In rear junction (RJ)-SHJ solar cells, the (n)c-Si bulk is known to support the lateral electron transport at maximum power point injection level, provided that the contact resistance of the front contact stack is sufficiently low. This enables experimental RJ-SHJ solar cell architectures featuring a localized front carrier-selective passivating contact exclusively covering the area contacted by the metal grid. Herein, a top-down approach to the synthesis of this type of architecture is studied and its optical and electrical performance applied to different (n)-type contacts are investigated. Additionally, the potential of the localized contact architecture through Cu-plated RJ-SHJ solar cells is demonstrated. These solar cell demonstrators feature high short-circuit current density of 40.5 mA cm−2, without significantly compromising their open-circuit voltage or fill factor, enabling efficiencies well above 23%, a 2%abs improvement compared to their state before localization of the front contact.
AB - Throughout the development of silicon heterojunction (SHJ) solar cells, the transparent conductive oxide has been regarded as an essential component of their front electrode, facilitating lateral charge transport of photogenerated carriers toward the front metal grid fingers. In rear junction (RJ)-SHJ solar cells, the (n)c-Si bulk is known to support the lateral electron transport at maximum power point injection level, provided that the contact resistance of the front contact stack is sufficiently low. This enables experimental RJ-SHJ solar cell architectures featuring a localized front carrier-selective passivating contact exclusively covering the area contacted by the metal grid. Herein, a top-down approach to the synthesis of this type of architecture is studied and its optical and electrical performance applied to different (n)-type contacts are investigated. Additionally, the potential of the localized contact architecture through Cu-plated RJ-SHJ solar cells is demonstrated. These solar cell demonstrators feature high short-circuit current density of 40.5 mA cm−2, without significantly compromising their open-circuit voltage or fill factor, enabling efficiencies well above 23%, a 2%abs improvement compared to their state before localization of the front contact.
KW - contact resistances
KW - electron-selective contacts
KW - localized contacts
KW - silicon heterojunction solar cells
KW - transparent conductive oxides
UR - http://www.scopus.com/inward/record.url?scp=105001692017&partnerID=8YFLogxK
U2 - 10.1002/solr.202400898
DO - 10.1002/solr.202400898
M3 - Article
AN - SCOPUS:105001692017
SN - 2367-198X
VL - 9
JO - Solar RRL
JF - Solar RRL
IS - 7
M1 - 2400898
ER -