TY - JOUR
T1 - Singlet Fission in Crystalline Organic Materials
T2 - Recent Insights and Future Directions
AU - Felter, Kevin M.
AU - Grozema, Ferdinand C.
PY - 2019
Y1 - 2019
N2 - Singlet fission (SF) involves the conversion of one excited singlet state into two lower excited triplet states and has received considerable renewed attention over the past decade. This Perspective highlights recent developments and emerging concepts of SF in solid-state crystalline materials. Recent experiments showed the crucial role of vibrational modes in speeding up SF, and theoretical modeling has started to define an optimal energetic landscape and intermolecular orientation of chromophores for highly efficient singlet fission. A critical analysis of these developments leads to directions for future research to eventually find singlet fission chromophores with excellent optoelectronic properties.
AB - Singlet fission (SF) involves the conversion of one excited singlet state into two lower excited triplet states and has received considerable renewed attention over the past decade. This Perspective highlights recent developments and emerging concepts of SF in solid-state crystalline materials. Recent experiments showed the crucial role of vibrational modes in speeding up SF, and theoretical modeling has started to define an optimal energetic landscape and intermolecular orientation of chromophores for highly efficient singlet fission. A critical analysis of these developments leads to directions for future research to eventually find singlet fission chromophores with excellent optoelectronic properties.
UR - http://www.scopus.com/inward/record.url?scp=85075043029&partnerID=8YFLogxK
U2 - 10.1021/acs.jpclett.9b00754
DO - 10.1021/acs.jpclett.9b00754
M3 - Article
AN - SCOPUS:85075043029
SN - 1948-7185
VL - 10
SP - 7208
EP - 7214
JO - Journal of Physical Chemistry Letters
JF - Journal of Physical Chemistry Letters
IS - 22
ER -