Solid-state molecular nanomagnet inclusion into a magnetic metal-organic framework: interplay of the magnetic properties

M Mon, A Pascual-Alvarez, TM Grancha, J Cano, J Ferrando-Soria, F Lloret, J Gascon, J Pasan, D Armentano, More Authors

Research output: Contribution to journalArticleScientificpeer-review

62 Citations (Scopus)

Abstract

Single-ion magnets (SIMs) are the smallest possible magnetic devices and are a controllable, bottom-up approach to nanoscale magnetism with potential applications in quantum computing and high-density information storage. In this work, we take advantage of the promising, but yet insufficiently explored, solid-state chemistry of metal–organic
frameworks (MOFs) to report the single-crystal to single-crystal inclusion of such molecular nanomagnets within the pores of a magnetic MOF. The resulting host– guest supramolecular aggregate is used as a playground in the first in-depth study on the interplay between the internal magnetic field created by the long-range magnetic ordering
of the structured MOF and the slow magnetic relaxationof the SIM
Original languageEnglish
Pages (from-to)539-545
JournalChemistry a European Journal
Volume22
Issue number2
DOIs
Publication statusPublished - 2016

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