Abstract
Single-ion magnets (SIMs) are the smallest possible magnetic devices and are a controllable, bottom-up approach to nanoscale magnetism with potential applications in quantum computing and high-density information storage. In this work, we take advantage of the promising, but yet insufficiently explored, solid-state chemistry of metal–organic
frameworks (MOFs) to report the single-crystal to single-crystal inclusion of such molecular nanomagnets within the pores of a magnetic MOF. The resulting host– guest supramolecular aggregate is used as a playground in the first in-depth study on the interplay between the internal magnetic field created by the long-range magnetic ordering
of the structured MOF and the slow magnetic relaxationof the SIM
frameworks (MOFs) to report the single-crystal to single-crystal inclusion of such molecular nanomagnets within the pores of a magnetic MOF. The resulting host– guest supramolecular aggregate is used as a playground in the first in-depth study on the interplay between the internal magnetic field created by the long-range magnetic ordering
of the structured MOF and the slow magnetic relaxationof the SIM
Original language | English |
---|---|
Pages (from-to) | 539-545 |
Journal | Chemistry a European Journal |
Volume | 22 |
Issue number | 2 |
DOIs | |
Publication status | Published - 2016 |