Spill Behaviour of Hydrogen Carriers as Alternative Fuels for Ships

– Hydrogen carriers, such as liquid organic hydrogen carriers (LOHCs) and borohydrides, are promising zero-emission alternative fuels for ships. Bringing these hydrogen carriers on board, however, creates new challenges. A major challenge is their spill behaviour. Knowing the spill behaviour is paramount to avoid large-scale environmental disasters. This paper investigates the spill behaviour of four hydrogen carriers (and their conjugates): sodium borohydride, ammonia borane, dibenzyltoluene, and n-ethylcarbazole. The hydrogen carriers were all dissolved in artificial seawater to test their behaviour. Sodium borohydride reacts with seawater, as it also reacts with pure water. However, contrary to expectations, it reacts faster with seawater than regular water. The reaction mechanism behind this is unknown. Ammonia borane does not visibly react with normal water or with seawater. Dibenzyltoluene sinks and forms tiny bubbles which are easily perturbed. Unfortunately, perhydro dibenzyltoluene could not be tested due to technical problems. N-ethylcarbazole breaks up into smaller pieces and predominantly stays afloat, likely due to the surface tension of water. Perhydro n-ethylcarbazole floats but is barely visible in seawater due to its transparency. Preventive measures must be established to avoid large-scale spills if these substances are utilised on ships, as they are likely challenging to clean up.