TY - JOUR
T1 - Synthesis and Transport Studies of a Cofacial Porphyrin Cyclophane
AU - Zwick, Patrick
AU - Hsu, Chunwei
AU - El Abbassi, Maria
AU - Fuhr, Olaf
AU - Fenske, Dieter
AU - Dulić, Diana
AU - Van Der Zant, Herre S.J.
AU - Mayor, Marcel
N1 - Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.
PY - 2020
Y1 - 2020
N2 - Porphyrin cyclophane 1, consisting of two rigidly fixed but still movable cofacial porphyrins and exposing acetate-masked thiols in opposed directions of the macrocycle, is designed, synthesized, and characterized. The functional cyclophane 1, as pioneer of mechanosensitive 3D materials, forms stable single-molecule junctions in a mechanically controlled break-junction setup. Its reliable integration in a single-molecule junction is a fundamental prerequisite to explore the potential of these structures as mechanically triggered functional units and devices.
AB - Porphyrin cyclophane 1, consisting of two rigidly fixed but still movable cofacial porphyrins and exposing acetate-masked thiols in opposed directions of the macrocycle, is designed, synthesized, and characterized. The functional cyclophane 1, as pioneer of mechanosensitive 3D materials, forms stable single-molecule junctions in a mechanically controlled break-junction setup. Its reliable integration in a single-molecule junction is a fundamental prerequisite to explore the potential of these structures as mechanically triggered functional units and devices.
UR - http://www.scopus.com/inward/record.url?scp=85096588702&partnerID=8YFLogxK
U2 - 10.1021/acs.joc.0c01957
DO - 10.1021/acs.joc.0c01957
M3 - Article
AN - SCOPUS:85096588702
SN - 0022-3263
VL - 85
SP - 15072
EP - 15081
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 23
ER -