Temperature-Dependent Supramolecular Isomerism of Lutetium-Aminoterephthalate Metal-Organic Frameworks: Synthesis, Crystallography, and Physical Properties

Alla Dikhtiarenko; Pablo Serra-Crespo; S. Castellanos Ortega; A. Pustovarenko; Rafael Mendoza-Merono; Santiago García-Granda; J. Gascon

doi:10.1021/acs.cgd.6b00274

Temperature-Dependent Supramolecular Isomerism of Lutetium-Aminoterephthalate Metal-Organic Frameworks: Synthesis, Crystallography, and Physical Properties

Alla Dikhtiarenko
, Pablo Serra-Crespo
, S. Castellanos Ortega
, A. Pustovarenko
, Rafael Mendoza-Merono
, Santiago García-Granda
, J. Gascon^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

23 Citations (Scopus)

96 Downloads (Pure)

Abstract

Three supramolecular isomers of lutetium metal-organic framework, {Lu₂(H₂O)₄(ATA)₃·4H₂O}_n (Lu-ATA@RT), {Lu₂(H₂O)₂(C₃H₇NO)₂(ATA)₃}_n (Lu-ATA@100), and {Lu₂(C₃H₇NO)(ATA)₃}_n (Lu-ATA@150), have been obtained from the reaction of Lu(NO₃)₃·6H₂O with 2-aminoterephthalic acid (ATA) at different temperatures. The resulting structures of Lu-ATA metal-organic frameworks depend on the temperature applied during the synthesis, revealing a temperature-susceptible supramolecular isomerism. Single-crystal X-ray diffraction analyses suggest that new compounds with formula {Lu₂(S)_x(ATA)₃}_n (S = solvent: H₂O, DMF) display different three-dimensional architectures which consist of dinuclear lutetium building units. The supramolecular isomer Lu-ATA@RT, formed at room temperature, has a pcu-net topology, while its double interpenetrated analogue Lu-ATA@100 assembles at 100 °C under hydrothermal conditions. Hydrothermal synthesis at 150 °C affords formation of the dense Lu-ATA@150 cage-like framework displaying a new hexagonal-packed net topology. All Lu-ATA isomeric phases are porous and display different gas-uptake behavior toward carbon dioxide as a function of polymeric network arrangement. The luminescent properties of Lu-ATA frameworks in the solid state as well as in suspension in the presence of different solvents reveal a solvent-dependent emission.

Original language	English
Pages (from-to)	5636-5645
Number of pages	10
Journal	Crystal Growth & Design
Volume	16
Issue number	10
DOIs	https://doi.org/10.1021/acs.cgd.6b00274
Publication status	Published - 5 Oct 2016

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Dikhtiarenko, A., Serra-Crespo, P., Castellanos Ortega, S., Pustovarenko, A., Mendoza-Merono, R., García-Granda, S., & Gascon, J. (2016). Temperature-Dependent Supramolecular Isomerism of Lutetium-Aminoterephthalate Metal-Organic Frameworks: Synthesis, Crystallography, and Physical Properties. Crystal Growth & Design, 16(10), 5636-5645. https://doi.org/10.1021/acs.cgd.6b00274

@article{2ac2ca06bbb24c8da22c589132dc85e0,

title = "Temperature-Dependent Supramolecular Isomerism of Lutetium-Aminoterephthalate Metal-Organic Frameworks: Synthesis, Crystallography, and Physical Properties",

abstract = "Three supramolecular isomers of lutetium metal-organic framework, \{Lu2(H2O)4(ATA)3·4H2O\}n (Lu-ATA@RT), \{Lu2(H2O)2(C3H7NO)2(ATA)3\}n (Lu-ATA@100), and \{Lu2(C3H7NO)(ATA)3\}n (Lu-ATA@150), have been obtained from the reaction of Lu(NO3)3·6H2O with 2-aminoterephthalic acid (ATA) at different temperatures. The resulting structures of Lu-ATA metal-organic frameworks depend on the temperature applied during the synthesis, revealing a temperature-susceptible supramolecular isomerism. Single-crystal X-ray diffraction analyses suggest that new compounds with formula \{Lu2(S)x(ATA)3\}n (S = solvent: H2O, DMF) display different three-dimensional architectures which consist of dinuclear lutetium building units. The supramolecular isomer Lu-ATA@RT, formed at room temperature, has a pcu-net topology, while its double interpenetrated analogue Lu-ATA@100 assembles at 100 °C under hydrothermal conditions. Hydrothermal synthesis at 150 °C affords formation of the dense Lu-ATA@150 cage-like framework displaying a new hexagonal-packed net topology. All Lu-ATA isomeric phases are porous and display different gas-uptake behavior toward carbon dioxide as a function of polymeric network arrangement. The luminescent properties of Lu-ATA frameworks in the solid state as well as in suspension in the presence of different solvents reveal a solvent-dependent emission.",

author = "Alla Dikhtiarenko and Pablo Serra-Crespo and \{Castellanos Ortega\}, S. and A. Pustovarenko and Rafael Mendoza-Merono and Santiago Garc{\'i}a-Granda and J. Gascon",

year = "2016",

month = oct,

day = "5",

doi = "10.1021/acs.cgd.6b00274",

language = "English",

volume = "16",

pages = "5636--5645",

journal = "Crystal Growth \& Design",

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Dikhtiarenko, A, Serra-Crespo, P, Castellanos Ortega, S, Pustovarenko, A, Mendoza-Merono, R, García-Granda, S & Gascon, J 2016, 'Temperature-Dependent Supramolecular Isomerism of Lutetium-Aminoterephthalate Metal-Organic Frameworks: Synthesis, Crystallography, and Physical Properties', Crystal Growth & Design, vol. 16, no. 10, pp. 5636-5645. https://doi.org/10.1021/acs.cgd.6b00274

Temperature-Dependent Supramolecular Isomerism of Lutetium-Aminoterephthalate Metal-Organic Frameworks: Synthesis, Crystallography, and Physical Properties. / Dikhtiarenko, Alla; Serra-Crespo, Pablo; Castellanos Ortega, S. et al.
In: Crystal Growth & Design, Vol. 16, No. 10, 05.10.2016, p. 5636-5645.

Research output: Contribution to journal › Article › Scientific › peer-review

TY - JOUR

T1 - Temperature-Dependent Supramolecular Isomerism of Lutetium-Aminoterephthalate Metal-Organic Frameworks

T2 - Synthesis, Crystallography, and Physical Properties

AU - Dikhtiarenko, Alla

AU - Serra-Crespo, Pablo

AU - Castellanos Ortega, S.

AU - Pustovarenko, A.

AU - Mendoza-Merono, Rafael

AU - García-Granda, Santiago

AU - Gascon, J.

PY - 2016/10/5

Y1 - 2016/10/5

N2 - Three supramolecular isomers of lutetium metal-organic framework, {Lu2(H2O)4(ATA)3·4H2O}n (Lu-ATA@RT), {Lu2(H2O)2(C3H7NO)2(ATA)3}n (Lu-ATA@100), and {Lu2(C3H7NO)(ATA)3}n (Lu-ATA@150), have been obtained from the reaction of Lu(NO3)3·6H2O with 2-aminoterephthalic acid (ATA) at different temperatures. The resulting structures of Lu-ATA metal-organic frameworks depend on the temperature applied during the synthesis, revealing a temperature-susceptible supramolecular isomerism. Single-crystal X-ray diffraction analyses suggest that new compounds with formula {Lu2(S)x(ATA)3}n (S = solvent: H2O, DMF) display different three-dimensional architectures which consist of dinuclear lutetium building units. The supramolecular isomer Lu-ATA@RT, formed at room temperature, has a pcu-net topology, while its double interpenetrated analogue Lu-ATA@100 assembles at 100 °C under hydrothermal conditions. Hydrothermal synthesis at 150 °C affords formation of the dense Lu-ATA@150 cage-like framework displaying a new hexagonal-packed net topology. All Lu-ATA isomeric phases are porous and display different gas-uptake behavior toward carbon dioxide as a function of polymeric network arrangement. The luminescent properties of Lu-ATA frameworks in the solid state as well as in suspension in the presence of different solvents reveal a solvent-dependent emission.

AB - Three supramolecular isomers of lutetium metal-organic framework, {Lu2(H2O)4(ATA)3·4H2O}n (Lu-ATA@RT), {Lu2(H2O)2(C3H7NO)2(ATA)3}n (Lu-ATA@100), and {Lu2(C3H7NO)(ATA)3}n (Lu-ATA@150), have been obtained from the reaction of Lu(NO3)3·6H2O with 2-aminoterephthalic acid (ATA) at different temperatures. The resulting structures of Lu-ATA metal-organic frameworks depend on the temperature applied during the synthesis, revealing a temperature-susceptible supramolecular isomerism. Single-crystal X-ray diffraction analyses suggest that new compounds with formula {Lu2(S)x(ATA)3}n (S = solvent: H2O, DMF) display different three-dimensional architectures which consist of dinuclear lutetium building units. The supramolecular isomer Lu-ATA@RT, formed at room temperature, has a pcu-net topology, while its double interpenetrated analogue Lu-ATA@100 assembles at 100 °C under hydrothermal conditions. Hydrothermal synthesis at 150 °C affords formation of the dense Lu-ATA@150 cage-like framework displaying a new hexagonal-packed net topology. All Lu-ATA isomeric phases are porous and display different gas-uptake behavior toward carbon dioxide as a function of polymeric network arrangement. The luminescent properties of Lu-ATA frameworks in the solid state as well as in suspension in the presence of different solvents reveal a solvent-dependent emission.

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IS - 10

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Temperature-Dependent Supramolecular Isomerism of Lutetium-Aminoterephthalate Metal-Organic Frameworks: Synthesis, Crystallography, and Physical Properties

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