Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems

J.A. Ocadiz flores; B.A.S. Rooijakkers; R. Konings; A.L. Smith

doi:10.3390/thermo1020009

Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems

J.A. Ocadiz flores, B.A.S. Rooijakkers, R. Konings, A.L. Smith

RST/Reactor Physics and Nuclear Materials

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Abstract

The ACl-ThCl (Formula presented.) (A = Li, Na, K) systems could be of relevance to the nuclear industry in the near future. A thermodynamic investigation of the three binary systems is presented herein. The excess Gibbs energy of the liquid solutions is described using the quasi-chemical formalism in the quadruplet approximation. The phase diagram optimisations are based on the experimental data available in the literature. The thermodynamic stability of the liquid solutions increases in the order Li < Na < K, in agreement with idealised interactions and structural models.

Original language	English
Pages (from-to)	122-133
Number of pages	1
Journal	Thermo
Volume	1
Issue number	2
DOIs	https://doi.org/10.3390/thermo1020009
Publication status	Published - 2021

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10.3390/thermo1020009

thermo-01-00009-v2Final published version, 404 KBLicence: CC BY

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abstract = "The ACl-ThCl (Formula presented.) (A = Li, Na, K) systems could be of relevance to the nuclear industry in the near future. A thermodynamic investigation of the three binary systems is presented herein. The excess Gibbs energy of the liquid solutions is described using the quasi-chemical formalism in the quadruplet approximation. The phase diagram optimisations are based on the experimental data available in the literature. The thermodynamic stability of the liquid solutions increases in the order Li < Na < K, in agreement with idealised interactions and structural models.",

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AU - Konings, R.

AU - Smith, A.L.

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N2 - The ACl-ThCl (Formula presented.) (A = Li, Na, K) systems could be of relevance to the nuclear industry in the near future. A thermodynamic investigation of the three binary systems is presented herein. The excess Gibbs energy of the liquid solutions is described using the quasi-chemical formalism in the quadruplet approximation. The phase diagram optimisations are based on the experimental data available in the literature. The thermodynamic stability of the liquid solutions increases in the order Li < Na < K, in agreement with idealised interactions and structural models.

AB - The ACl-ThCl (Formula presented.) (A = Li, Na, K) systems could be of relevance to the nuclear industry in the near future. A thermodynamic investigation of the three binary systems is presented herein. The excess Gibbs energy of the liquid solutions is described using the quasi-chemical formalism in the quadruplet approximation. The phase diagram optimisations are based on the experimental data available in the literature. The thermodynamic stability of the liquid solutions increases in the order Li < Na < K, in agreement with idealised interactions and structural models.

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Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems

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Correction: Ocádiz Flores et al. Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems: Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems (Thermo, (2021), 1, 2, (122-133), 10.3390/thermo1020009)

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