Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems

J.A. Ocadiz flores; B.A.S. Rooijakkers; R. Konings; A.L. Smith

doi:10.3390/thermo1020009

Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems

J.A. Ocadiz flores, B.A.S. Rooijakkers, R. Konings, A.L. Smith

RST/Reactor Physics and Nuclear Materials

Research output: Contribution to journal › Comment/Letter to the editor › Scientific › peer-review

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Abstract

The ACl-ThCl4 (A = Li, Na, K) systems could be of relevance to the nuclear industry in the near future. A thermodynamic investigation of the three binary systems is presented herein. The excess Gibbs energy of the liquid solutions is described using the quasi-chemical formalism in the quadruplet approximation. The phase diagram optimisations are based on the experimental data available in the literature. The thermodynamic stability of the liquid solutions increases in the order
Li ă Na ă K, in agreement with idealised interactions and structural models

Original language	English
Pages (from-to)	122-133
Journal	Thermo
Volume	2
Issue number	4
DOIs	https://doi.org/10.3390/thermo1020009
Publication status	Published - 2021

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thermo-01-00009-v2Final published version, 404 KBLicence: CC BY

1 Comment/Letter to the editor

Correction: Ocádiz Flores et al. Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems
Ocadiz flores, J. A., Rooijakkers, B. A. S., Konings, R. & Smith, A. L., 2022, In: Thermo. 2, 4, p. 394-400
Research output: Contribution to journal › Comment/Letter to the editor › Scientific › peer-review

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title = "Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems",

abstract = "The ACl-ThCl4 (A = Li, Na, K) systems could be of relevance to the nuclear industry in the near future. A thermodynamic investigation of the three binary systems is presented herein. The excess Gibbs energy of the liquid solutions is described using the quasi-chemical formalism in the quadruplet approximation. The phase diagram optimisations are based on the experimental data available in the literature. The thermodynamic stability of the liquid solutions increases in the orderLi {\u a} Na {\u a} K, in agreement with idealised interactions and structural models",

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AU - Ocadiz flores, J.A.

AU - Rooijakkers, B.A.S.

AU - Konings, R.

AU - Smith, A.L.

PY - 2021

Y1 - 2021

N2 - The ACl-ThCl4 (A = Li, Na, K) systems could be of relevance to the nuclear industry in the near future. A thermodynamic investigation of the three binary systems is presented herein. The excess Gibbs energy of the liquid solutions is described using the quasi-chemical formalism in the quadruplet approximation. The phase diagram optimisations are based on the experimental data available in the literature. The thermodynamic stability of the liquid solutions increases in the orderLi ă Na ă K, in agreement with idealised interactions and structural models

AB - The ACl-ThCl4 (A = Li, Na, K) systems could be of relevance to the nuclear industry in the near future. A thermodynamic investigation of the three binary systems is presented herein. The excess Gibbs energy of the liquid solutions is described using the quasi-chemical formalism in the quadruplet approximation. The phase diagram optimisations are based on the experimental data available in the literature. The thermodynamic stability of the liquid solutions increases in the orderLi ă Na ă K, in agreement with idealised interactions and structural models

U2 - 10.3390/thermo1020009

DO - 10.3390/thermo1020009

M3 - Comment/Letter to the editor

VL - 2

SP - 122

EP - 133

JO - Thermo

JF - Thermo

SN - 2673-7264

IS - 4

ER -

Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems

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Correction: Ocádiz Flores et al. Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems

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