Effects of pore water-rock reaction on heat extraction from the karst geothermal reservoirs: Based on the dual media model

Fractures and caves are the main flow and storage channels for the karst geothermal reservoirs, and the water-rock reaction within them significantly affects the thermal performance. Most previous studies concentrated on the fractures, disregarding the impact of the pore water-rock reaction. The objective of this study is to explore the importance of pore water-rock reactions and identify the influence of various parameters when considering pore and fracture water-rock reactions. A 3D thermal-hydraulic-chemical coupling model considering dual media of pores and fractures was developed. The importance of pore water-rock reactions is demonstrated, and quantitatively characterize the effect of injection temperature (T_in), injection rate (Q_in), injection concentration (c_in), and ratio of the reaction-specific surface area between pore and fracture (A_p/A_f) on the thermal performance. Results indicate that the pore water-rock reaction drastically affects the hydraulic conductivity and pressure difference, even leading to an opposite trend. The influence of water-rock reaction in pores on fracture deformation is regulated by A_p/A_f, which augments with A_p/A_f. The relative contribution of A_p/A_f to production temperature, net thermal power, pressure difference, and hydraulic conductivity are 12.8%, 4.1%, 6.8%, and 13.7%, respectively. This study provides a significant guide for accurate production prediction and exploitation of karst-based geothermal reservoirs.