TY - JOUR
T1 - Fischer-Tropsch synthesis over lignin-derived cobalt-containing porous carbon fiber catalysts
AU - Valero-Romero, M. J.
AU - García-Mateos, F. J.
AU - Kapteijn, Freek
AU - Rodríguez-Mirasol, J.
AU - Cordero, T.
PY - 2023
Y1 - 2023
N2 - Cobalt-containing lignin-based fibers were synthesized in one step by electrospinning of Alcell lignin solutions as carbon precursor, a low-cost and renewable co-product of the paper making industry. The lignin fibers were thermostabilized in air to avoid the fusion during the carbonization process between 500 and 800 °C to obtain cobalt-containing porous carbon submicron fibers. These carbon fibers catalysts were studied for the Low-Temperature Fischer-Tropsch synthesis. The lignin-derived fibers containing Co catalyst located on the overall carbon fiber surface (internal and external) heat-treated at 500 °C (Co@CF-500) showed the best catalytic performance after 70 h on stream, with 75% and 60% selectivity to C5+ at 220 °C and H2/CO ratios of 1 and 2, respectively, attributed to the high Co dispersion, optimal Co-particle size and better Co accessibility. Higher heat-treatment temperatures leaded to Co-containing carbon fibers with larger metallic cobalt nanoparticles encapsulated in graphitic-type carbon, which rendered them inaccessible for FTS.
AB - Cobalt-containing lignin-based fibers were synthesized in one step by electrospinning of Alcell lignin solutions as carbon precursor, a low-cost and renewable co-product of the paper making industry. The lignin fibers were thermostabilized in air to avoid the fusion during the carbonization process between 500 and 800 °C to obtain cobalt-containing porous carbon submicron fibers. These carbon fibers catalysts were studied for the Low-Temperature Fischer-Tropsch synthesis. The lignin-derived fibers containing Co catalyst located on the overall carbon fiber surface (internal and external) heat-treated at 500 °C (Co@CF-500) showed the best catalytic performance after 70 h on stream, with 75% and 60% selectivity to C5+ at 220 °C and H2/CO ratios of 1 and 2, respectively, attributed to the high Co dispersion, optimal Co-particle size and better Co accessibility. Higher heat-treatment temperatures leaded to Co-containing carbon fibers with larger metallic cobalt nanoparticles encapsulated in graphitic-type carbon, which rendered them inaccessible for FTS.
KW - Co-containing carbon fibers
KW - Electrospinning
KW - Fischer-Tropsch synthesis
KW - Lignin
UR - http://www.scopus.com/inward/record.url?scp=85140048809&partnerID=8YFLogxK
U2 - 10.1016/j.apcatb.2022.122078
DO - 10.1016/j.apcatb.2022.122078
M3 - Article
AN - SCOPUS:85140048809
SN - 0926-3373
VL - 321
JO - Applied Catalysis B: Environmental
JF - Applied Catalysis B: Environmental
M1 - 122078
ER -