TY - JOUR
T1 - Generator-collector electrochemical sensor configurations based on track-Etch membrane separated platinum leaves
AU - Zafarani, Hamid Reza
AU - Rassaei, Liza
AU - Sudhölter, Ernst J.R.
AU - Aaronson, Barak D.B.
AU - Marken, Frank
PY - 2018
Y1 - 2018
N2 - We report a novel, simple and cheap generator-collector electrode system, employing platinum leaves, with micron-sized pores and typically 100-300. nm thickness, sandwiched with a porous track etch membrane spacer with typically 30. nm diameter pores. The electrode assembly is sealed into a polymer lamination pouch with one side 2. mm diameter exposed to electrolyte solution. The generator electrode with sweeping potential (top or bottom electrode) shows transient current with high capacitive current component. The collector electrode with fixed potential shows well-defined steady state current response at low potential sweep rates. The fabricated device shows good performance in monitoring both 1,1'-ferrocenedimethanol oxidation and proton reduction redox processes. Oxygen sensor signals are assigned to a lowering of the steady state proton reduction current.
AB - We report a novel, simple and cheap generator-collector electrode system, employing platinum leaves, with micron-sized pores and typically 100-300. nm thickness, sandwiched with a porous track etch membrane spacer with typically 30. nm diameter pores. The electrode assembly is sealed into a polymer lamination pouch with one side 2. mm diameter exposed to electrolyte solution. The generator electrode with sweeping potential (top or bottom electrode) shows transient current with high capacitive current component. The collector electrode with fixed potential shows well-defined steady state current response at low potential sweep rates. The fabricated device shows good performance in monitoring both 1,1'-ferrocenedimethanol oxidation and proton reduction redox processes. Oxygen sensor signals are assigned to a lowering of the steady state proton reduction current.
KW - Amplification
KW - Dual-plate sensor
KW - Hydrogen
KW - Oxygen
KW - Platinum
KW - Voltammetry
UR - http://www.scopus.com/inward/record.url?scp=85030642592&partnerID=8YFLogxK
U2 - 10.1016/j.snb.2017.09.110
DO - 10.1016/j.snb.2017.09.110
M3 - Article
AN - SCOPUS:85030642592
SN - 0925-4005
VL - 255
SP - 2904
EP - 2909
JO - Sensors and Actuators B: Chemical: international journal devoted to research and development of physical and chemical transducers
JF - Sensors and Actuators B: Chemical: international journal devoted to research and development of physical and chemical transducers
IS - 3
ER -