Illuminating the nature and behavior of the active center: The key for photocatalytic H2 production in Co@NH2-MIL-125(Ti)

Ana Iglesias-Juez*, Sonia Castellanos, Manuel Monte, Dmitrii Osadchii, Giovanni Agostini, Maxim A. Nasalevich, Jara G. Santaclara, Alma I. Olivos Suarez, Sergey L. Veber, Matvey V. Fedin, Jorge Gascón

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

16 Citations (Scopus)

Abstract

Advanced atomically resolved characterization methods unveil the mechanism of a promising photocatalytic Co@MOF(Ti) system for H2 production. The combination of X-ray absorption spectroscopy (XAS) and electron paramagnetic resonance (EPR) experiments allows for the characterization of atomic and electronic rearrangements in the photoinduced species. This information provides the basis for the optimization of photocatalyst design.

Original languageEnglish
Pages (from-to)17318-17322
JournalJournal of Materials Chemistry A
Volume6
Issue number36
DOIs
Publication statusPublished - 2018

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