TY - JOUR
T1 - Local scanning electrochemical microscopy analysis of a lithium-based conversion layer on AA2024-T3 at progressive stages of formation
AU - Li, Ziyu
AU - Li, Gaojie
AU - Visser, Peter
AU - Homborg, Axel
AU - Gonzalez-Garcia, Yaiza
AU - Mol, Arjan
PY - 2023
Y1 - 2023
N2 - Scanning electrochemical microscopy (SECM) is employed to characterize the evolution of local electrochemical surface activity during lithium-based conversion layer formation on legacy aerospace aluminium alloy AA2024-T3. Initially, three types of studied intermetallic particles - S-, θ- and constituent phases - act as active cathodic areas. Subsequently, θ- and constituent phases show passivation preceding that of S-phase particles during the later conversion layer formation stages. The entire surface, including the matrix region, shows a higher reactivity at the beginning and then gradually shows decreasing reactivity. Hydrogen evolution-generated bubbles attach to the alloy surface and locally hinder the conversion layer formation, weakening the corrosion protection the conversion layer provides at those locations.
AB - Scanning electrochemical microscopy (SECM) is employed to characterize the evolution of local electrochemical surface activity during lithium-based conversion layer formation on legacy aerospace aluminium alloy AA2024-T3. Initially, three types of studied intermetallic particles - S-, θ- and constituent phases - act as active cathodic areas. Subsequently, θ- and constituent phases show passivation preceding that of S-phase particles during the later conversion layer formation stages. The entire surface, including the matrix region, shows a higher reactivity at the beginning and then gradually shows decreasing reactivity. Hydrogen evolution-generated bubbles attach to the alloy surface and locally hinder the conversion layer formation, weakening the corrosion protection the conversion layer provides at those locations.
KW - Aluminium alloy
KW - Inhibitor
KW - Lithium-based conversion layer
KW - SECM
UR - http://www.scopus.com/inward/record.url?scp=85172284427&partnerID=8YFLogxK
U2 - 10.1016/j.electacta.2023.143270
DO - 10.1016/j.electacta.2023.143270
M3 - Article
AN - SCOPUS:85172284427
SN - 0013-4686
VL - 469
JO - Electrochimica Acta
JF - Electrochimica Acta
M1 - 143270
ER -