Monitoring and inverse modelling of hydrogeochemical processes during managed aquifer recharge in Southwestern Bangladesh

Managed Aquifer Recharge (MAR) has been applied as Aquifer Storage, Transfer, and Recovery (ASTR) to provide fresh drinking water for local communities at 99 locations in southwest Bangladesh since 2009. Aerobic freshwater from ponds is filtered and subsequently infiltrated into anaerobic shallow brackish aquifers. At approximately 45% of these sites, relatively higher levels of Fe and As were observed in recovered water, which requires a better understanding of the hydrogeochemical processes that govern the Fe, Mn, and As levels in these MAR systems. Therefore, two representative sites with As above (74 ± 11 μg/L at site GMF11) and below (19 ± 6 μg/L at site JJS91), the Bangladesh drinking water standard of 50 μg/L were weekly monitored on hydrochemical changes from Dec 2017 to Dec 2018. Hydrogeochemical processes occurring during storage were quantified with inverse and forward geochemical mass balance models developed with PHREEQC. The following processes explained the changes in water quality: 1) mixing of infiltration water with native groundwater (∼90%:∼10%); 2) consumption of O₂ by a) dissolved Fe²⁺ that subsequently precipitated as Fe(OH)₃ at GMF11 and by b) dissolved and sedimentary organic matter (OM) at site JJS91; 3) reduction of SO₄ coupled to the oxidation of OM at both sites; and 4) mixing corrosion and freshening induced cation-exchange (Ca sorption; Na desorption) triggering calcite and siderite dissolution at GMF11. Dissolution of these carbonate minerals occurred to a lesser extent at JJS91, while cation exchange (Na sorption; Ca desorption) suggested that the freshwater was displaced by brackish groundwater because of inadequate infiltration at JJS91. Distinct pH values in recovered water reflected the dominance of Fe²⁺ versus OM oxidation. Siderite dissolution led to 4.3 ± 3.1 and 1.0 ± 0.5 mg/L Fe in recovered water at GMF11 and JJS91, respectively. Elevated As and Mn levels in recovered water were caused for max. 20% by mixing with native groundwater and for min. 80% by mobilization processes, mainly by desorption of As from Fe-oxides and by the dissolution of Mn-bearing siderite. Recommendations are provided to improve recovered water quality.