TY - JOUR
T1 - On the Mechanism Underlying the Direct Conversion of Methane to Methanol by Copper Hosted in Zeolites; Braiding Cu K-Edge XANES and Reactivity Studies
AU - Newton, Mark A.
AU - Knorpp, Amy J.
AU - Pinar, Ana B.
AU - Sushkevich, Vitaly L.
AU - Palagin, Dennis
AU - Van Bokhoven, Jeroen A.
PY - 2018/8/15
Y1 - 2018/8/15
N2 - The application and quantification of in situ copper K-edge X-ray absorption near-edge structure (XANES), when linked to independently made reactor-based studies of methanol production, result in a majority relation between the production of CuI and methanol from methane that complies with the expectations of a two-electron mechanism founded upon CuII/CuI redox couples.
AB - The application and quantification of in situ copper K-edge X-ray absorption near-edge structure (XANES), when linked to independently made reactor-based studies of methanol production, result in a majority relation between the production of CuI and methanol from methane that complies with the expectations of a two-electron mechanism founded upon CuII/CuI redox couples.
UR - http://www.scopus.com/inward/record.url?scp=85051655471&partnerID=8YFLogxK
U2 - 10.1021/jacs.8b05139
DO - 10.1021/jacs.8b05139
M3 - Article
C2 - 30071725
AN - SCOPUS:85051655471
SN - 0002-7863
VL - 140
SP - 10090
EP - 10093
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 32
ER -