Porous Metal-Organic Framework CUK-1 for Adsorption Heat Allocation toward Green Applications of Natural Refrigerant Water

Ji Sun Lee, Ji Woong Yoon, Paulo G.M. Mileo, Kyung Ho Cho, Jaedeuk Park, Kiwoong Kim, Hyungjun Kim, Martijn F. de Lange, Freek Kapteijn, More Authors

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11 Citations (Scopus)
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Abstract

The development of new water adsorbents that are hydrothermally stable and can operate more efficiently than existing materials is essential for the advancement of water adsorption-driven chillers. Most of the existing benchmark materials and related systems in this field suffer from clear limitations that must be overcome to meet global requirements for sustainable and green energy production and utilization. Here, we report the energy-efficient water sorption properties of three isostructural metal-organic frameworks (MOFs) based on the simple ligand pyridine-2,4-dicarboxylate, named M-CUK-1 [M3(μ3-OH)2(2,4-pdc)2] (where M = Co2+, Ni2+, or Mg2+). The highly hydrothermally stable CUK-1 series feature step-like water adsorption isotherms, relatively high H2O sorption capacities between P/P0 = 0.10-0.25, stable cycling, facile regeneration, and, most importantly, benchmark coefficient of performance values for cooling and heating at a low driving temperature. Furthermore, these MOFs are prepared under green hydrothermal conditions in aqueous solutions. Our joint experimental-computational approach revealed that M-CUK-1 integrates several optimal features, resulting in promising materials as advanced water adsorbents for adsorption-driven cooling and heating applications.

Original languageEnglish
Pages (from-to)25778-25789
JournalACS applied materials & interfaces
Volume11
Issue number29
DOIs
Publication statusPublished - 2019

Keywords

  • coefficient of performance
  • M-CUK-1
  • metal−organic framework
  • SAPO-34
  • water sorption

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    Lee, J. S., Yoon, J. W., Mileo, P. G. M., Cho, K. H., Park, J., Kim, K., Kim, H., de Lange, M. F., Kapteijn, F., & More Authors (2019). Porous Metal-Organic Framework CUK-1 for Adsorption Heat Allocation toward Green Applications of Natural Refrigerant Water. ACS applied materials & interfaces, 11(29), 25778-25789. https://doi.org/10.1021/acsami.9b02605