Spatially Resolved Band Gap and Dielectric Function in Two-Dimensional Materials from Electron Energy Loss Spectroscopy

Abel Brokkelkamp, Jaco Ter Hoeve, Isabel Postmes, Sabrya E. Van Heijst, Louis Maduro, Albert V. Davydov, Sergiy Krylyuk, Juan Rojo, Sonia Conesa-Boj*

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

17 Downloads (Pure)

Abstract

The electronic properties of two-dimensional (2D) materials depend sensitively on the underlying atomic arrangement down to the monolayer level. Here we present a novel strategy for the determination of the band gap and complex dielectric function in 2D materials achieving a spatial resolution down to a few nanometers. This approach is based on machine learning techniques developed in particle physics and makes possible the automated processing and interpretation of spectral images from electron energy loss spectroscopy (EELS). Individual spectra are classified as a function of the thickness with K-means clustering, and then used to train a deep-learning model of the zero-loss peak background. As a proof of concept we assess the band gap and dielectric function of InSe flakes and polytypic WS2 nanoflowers and correlate these electrical properties with the local thickness. Our flexible approach is generalizable to other nanostructured materials and to higher-dimensional spectroscopies and is made available as a new release of the open-source EELSfitter framework.

Original languageEnglish
Pages (from-to)1255-1262
JournalJournal of Physical Chemistry A
Volume126
Issue number7
DOIs
Publication statusPublished - 2022

Fingerprint

Dive into the research topics of 'Spatially Resolved Band Gap and Dielectric Function in Two-Dimensional Materials from Electron Energy Loss Spectroscopy'. Together they form a unique fingerprint.

Cite this