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Abstract
This work investigates long-term photoelectrochemical hydrogen evolution (82 days) in 1 M HClO4 using a TiO2:H protected crystalline Si-based photocathode with metal-oxide-semiconductor (MOS) junctions. It is shown that day/night cycling leads to relatively rapid performance degradation while the photocurrent under the continuous light condition is relatively stable. We observed that the performance loss is mainly due to contamination of the catalytically active surface with carbonaceous material. By ultraviolet (UV) light exposure, we also observed that the activity can be restored, most likely due to photocatalytic degradation of organic compounds by the UV light excited TiO2 protection layer.
| Original language | English |
|---|---|
| Pages (from-to) | 106-109 |
| Number of pages | 4 |
| Journal | ChemElectroChem |
| Volume | 6 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2019 |
Bibliographical note
Accepted Author ManuscriptKeywords
- energy conversion
- hydrogen evolution reaction
- PECs
- titanium oxide
- water splitting
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Dive into the research topics of 'Durability Testing of Photoelectrochemical Hydrogen Production under Day/Night Light Cycled Conditions'. Together they form a unique fingerprint.Projects
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LEaDing Fellows
Gutierrez, A., Dols Perez, A., Bae, D., Sahoo, H., Wang, W., Lam, K. L., Raimondo, A., Steffelbauer, D. B., Lesne, E. L., Ragno, E., Amador, G. J., Šiaudinyte, L., Sand, M., Robinson Garcia, N., Abil, Z., Purkarthofer, E., Noardo, F., Tasić, J. K., Marin, L., Angeloni, L., loddo, M., Stockill, R. H. J., Franklin, S. W., Hensen, B. J., Dennis, M. J., Afroza Islam, S. T., Kim, T., Manzaneque Garcia, T., Tiringer, U., Marques Penha, F., Esteban Jurado, C., Timmermans, E., McCrum, I. T., Pool, F., Forn-Cuní, G., Will, G., Barrett, H. E., Everett, J. A. C., Kostenzer, J., Luksenburg, J., Hirvasniemi, J., Desai, J., Ruibal, P., Albury, N. J., March, R., Eichengreen, A., Muok, A. R., Cochrane, A., Ravesteijn, B., Riumalló Herl, C. J., Meeusen, C., Biaggi, C., Granger, C., Cecil, C., Fosch Villaronga, E., Sánchez López, E. S., Loehrer, E., da Costa Gonçalves, F., Giardina, F., Wu, H., Gleitz, H. & Khatri, I.
2/01/17 → 1/05/22
Project: Research